@Irminsul I would've thought Sympathy for the Devil would have been the one Rolling Stones song you knew by name with your Metal background.
All of their stuff (well almost all) is awesome, but I guess I like "Gimme Shelter", "Bitch" (from "Sticky Fingers" I think) and one of my favorite later tunes of theirs is "Waiting On A Friend" from "Tattoo You". I love the sax part on that song!